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Possibly someone has had a spare key made without the transponder properly set up. Normally Peugeots come with two proper remote keys. FIAT often supply a remote key plus a small key without remote. The small key still has a transponder in though and starts the engine.Are you saying the key your using to start the vehicle is a plain key, no fob or plastic handle?
If so it's unlikely to have the transponder fitted and it will only unlock and turn the engine over.
You need the key with the black plastic end of fob. Inside is the transponder that operates the immobilizer.
I think that is the clue, your other half maybe has the key with the transponder?The one I have doesn’t have the body